Intergranular stress corrosion cracking igscc archives. Intergranular stress corrosion cracking initiation model of austenite. In recent years, failures of reactor internal components have been observed after the components have reached neutron fluence. There are two modes of stress corrosion cracking in austenitic stainless steels, namely intergranular and transgranular stress corrosion cracking, i. Boiling water reactors bwrs operate with very high purity water. The effect of surface property on the polarization behavior of hydrogen h 2 oxidation, oxygen o 2 reduction, and electrochemical corrosion potential ecp on type 304 stainless steel ss in high temperature, high purity water was studied. According to the electrochemical theory, this requires a condition along grain boundaries that makes them anodic to the rest of the microstructure so that corrosion. Dec 19, 2019 intergranular stress corrosion cracking igscc is a type of corrosion due to applied forces on the granular boundaries of a material. Oct 28, 2014 stress corrosion can be called stress corrosion cracking too.
Effects of hydrogen peroxide on intergranular stress. Field experience as well as laboratory test results are considered to illustrate how iascc already impacts plant operation. Intergranular stress corrosion cracking has occurred in bwr environments in nonsensitised, coldworked austenitic stainless steel materials. Intergranular stress corrosion cracking of welded steel twi. Evaluation of risk associated with intergranular stress corrosion cracking in boiling water reactor internals nuregcr6677. Polythionic acid stress corrosion cracking pascc is an affliction of many refineries processing sulfur containing feedstocks, and since that is the norm these days, most refiners reduce their susceptibility. Intergranular stress corrosion cracking scc of pipelines has been known to cause pipeline failure since the 1960s and is associated with a high ph, above 9, in the electrolyte in direct contact with the external pipe surface. There are several types of stress corrosion cracking scc. Intergranular stress corrosion cracking igscc has appeared in heat affected zones. Intergranular stress corrosion cracking igscc of bwr internal components has been identified as a technical issue of concern by both the nrc staff and the industry. Stress corrosion cracking odonnell consulting engineers.
The number of different types of components that have experienced cracking has increased over the years. The effects of stress strain factors, weld heat cycling, alloying elements and environmental factors on the stress corrosion cracking behavior in this system have. The interaction of corrosion fatigue and stresscorrosion. Bwr, author, abstractnote research and testing programs to study the initiation and growth of intergranular stress corrosion cracking in bwr stainless steel piping are described. Both bwr and pwr components can suffer from scc, which may have transgranular through the grains or intergranular along the grain boundaries. Stress corrosion cracking stress corrosion cracking is a failure mode caused by a combination of a susceptible material, stresses and an aggressive environment, figure 1. Stress corrosion cracking in light water reactors publications.
Kain 1 materials science division, bhabha atomic research centre, trombay, mumbai 400 085, india. This overview paper discusses each essential condition and the remedies for igscc that modify each condition. During heat treatment certain conditions can cause a material to become susceptible to intergranular attack a. This chapter focuses on the environmentally assisted cracking eac and, more specifically, the intergranular stress corrosion cracking igscc of austenitic stainless steels and nickel base alloys exposed to the recirculating boiling water reactor bwr environment. Corrosion evaluation of the pns citrox process for chemical. Effects of hydrogen peroxide on electrochemical corrosion. Intergranular stress corrosion cracking an overview. Intergranular stress corrosion cracking igscc has been detected in a number of boiling water reactor bwr vessel internals.
The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Transgranular stress corrosion cracking tgscc cracks run through the individual grains. Behavior of stress corrosion cracking for type 316l stainless. Intergranular stress corrosion cracking of austenitic stainless steel piping in bwrs has been a major safety concern since the early seventies. Fracture mechanicsbased testing was used to quantify the stress corrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950. An overview of intergranular stress corrosion cracking igscc in boiling water reactors bwrs is presented. Nrc position on intergranular stress corrosion cracking. For the bwr, the initiation of igscc of austenitic stainless steel and nickel. Nrc position on intergranular stress corrosion cracking igscc in bwr austenitic stainless steel piping generic letter 8801, supplement 1 the supplement provides acceptable alternative staff positions to some. Effect of water purity on intergranular stress corrosion cracking of stainless steel and nickel alloys in bwrs. A calculation model on intergranular stress corrosion cracking igscc initiation time of materials used in boiling water reactors bwrs has.
Intergranular stress corrosion cracking of austenitic stainless steel piping in bwrs. Effect of water purity on intergranular stress corrosion cracking of. Inter granular corrosion can be detected by ultrasonic and eddy current methods. The fundamental understanding and practical application of electrochemical mitigation of intergranular stress corrosion cracking igscc of structural materials in a boiling water reactor bwr is described. Quarterly progress report, october 1december 31, 1975. Intergranular stress corrosion cracking of austenitic stainless steels.
This is because of the intermolecular space that exists due to the interaction of two or more components. Intergranular stress corrosion cracking igscc is a type of corrosion due to applied forces on the granular boundaries of a material. Intergranular stress corrosion cracking igscc bwrvip325. The problem of stress corrosion cracking scc, which causes sudden failure of metals and other materials subjected to stress in corrosive environments, has a significant impact on a number of sectors including the oil and gas industries and nuclear power production. Request pdf intergranular stress corrosion cracking igscc in boiling water reactors bwrs this chapter focuses on the environmentally assisted cracking eac and, more specifically, the. May 22, 2015 intergranular stress corrosion cracking igscc of bwr internal components has been identified as a technical issue of concern by both the nrc staff and the industry. Bwr vessels are made of materials susceptible to intergranular stress corrosion cracking igscc, including. In recent years, failures of reactor internal components have been observed after the components have reached neutron fluence levels 5 x 10 20 ncm2 e 1 mev. Effects of hydrogen peroxide on intergranular stress corrosion cracking of stainless steel in high temperature water, i. Good practices and lessons learned international atomic energy agency vienna isbn 9789201172105 issn 19957807. Cracking of sensitized stainless steels inspectioneering. Description and experience intergranular stress corrosion cracking igscc is stress corrosion cracking where the grain boundaries of a susceptible material are cracked due to stress and an agressive. Technical basis for water chemistry control of igscc in boiling. Intergranular stress corrosion cracking of austenitic.
On july 25, 1994, the us nuclear regulatory commission nrc issued generic letter gl 9403 to obtain information needed to assess compliance with regulatory requirements regarding the structural integrity of core shrouds in domestic boiling water reactors bwrs. European corrosion congress eurocorr 2017 and 20th international corrosion congress and process safety congress 2017. Intergranular cracking of aisi 316ng stainless steel in bwr. This report begins with a brief description of the safety significance of intergranular stress corrosion cracking igscc as it relates to the design and function of bwr core shrouds and other internal. Transgranular stress corrosion cracking tgscc is the same as igscc, but the grain boundaries are not preferentially attacked 1, 2. Paul woollin twi ltd, granta park, great abington, cambridge, cb1 6al, uk. Intergranular stress corrosion cracking in rbmk reactors to assist countries operating rbmk reactors in addressing the issue in austenitic stainless steel 300 mm diameter piping. Intergranular stress corrosion cracking igscc is stress corrosion cracking.
Microstructural and microchemical mechanisms controlling. Intergranular stress corrosion cracking of bwr core. Intergranular stress corrosion cracking igscc in boiling. Stress corrosion cracking scc of type 316l stainless steels with controlled surface hardness distribution was investigated under simulated boiling water reactor bwr condition by creviced bent beam cbb tests. Sensitization refers to the precipitation of carbides at grain boundaries in a stainless steel or alloy, causing the steel or alloy to be. Intergranular stress corrosion cracking of core shrouds. Instrument penetrations in a nuclear plants reactor pressure vessel are susceptible to a type of degradation called stress corrosion cracking. Stress corrosion cracking can proceed in one of two ways. Paper presented at corrosion 2007, paper 07094, nashville, tennessee, 1115 march 2007. The number of different types of components that have experienced cracking.
It is associated with the simultaneous presence of a number of factors. Intergranular corrosion induced by environmental stresses is termed stress corrosion cracking. The evaluation of intergranular stress corrosion cracking. Gl 8801 addressed igscc near weldments in bwr piping that had occurred for almost 20 years. Stress corrosion cracking in aluminum alloys is characteristically intergranular.
Structural reliability improvement using inservice. It is a combination between tensile stress and a corrosive environment. Intergranular cracking proceeds along the grain boundaries whereas transgranular cracking does not have preferences for boundaries 69. Epri guidance improves managing stress corrosion cracking in. Stress corrosion cracking facts and how to reduce the. Irradiation assisted stress corrosion cracking iascc is a term which has been used in recent years to describe intergranular cracking showing little or no ductility which can occur in heavily irradiated struc. Boiling water reactor bwr vessel and internals project bwr reactor vessel instrument penetration handbook instrument penetrations in a nuclear plants reactor pressure vessel are susceptible to a type of degradation called stress corrosion cracking. Pdf intergranular cracking of aisi 316ng stainless steel. This report begins with a brief description of the safety significance of intergranular stress corrosion cracking igscc as it relates to the design and function of bwr core shrouds and other internal components. The influence of hydrogen water chemistry and platinum. Electrochemical mitigation of intergranular stress.
The core shroud is among the list of internals susceptible to igscc. Intergranular stress corrosion cracking igscc is stress corrosion cracking where the grain boundaries of a susceptible material are cracked due to stress and an agressive environment. Intergranular stress corrosion cracking scc of pipelines has been known to cause pipeline failure since the 1960s and is associated with a high ph, above 9, in the electrolyte in direct contact with the. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment.
Irradiationassisted stress corrosion cracking and impact on. Intergranular stress corrosion cracking igscc cracks propagate along the grain boundaries. Intergranular corrosion and stress corrosion larissacglima. Effects of hydrogen peroxide on intergranular stress corrosion cracking of stainless steel in high temperature water, iv journal of nuclear science and technology. Tsai boiling water reactor, bwr intergranular stress corrosion cracking, igscc hydrogen water chemistry, hwc noble metal chemical addition, nmca bwr igscc m ho 2 electrochemical corrosion. The evaluation of intergranular stress corrosion cracking problems of stainless steel piping in taiwan bwr 6 nuclear power plant. Citeseerx document details isaac councill, lee giles, pradeep teregowda. Irradiation assisted stress corrosion cracking iascc is a term which has been used in recent years to describe intergranular cracking showing little or no ductility which can occur in heavily irradiated struc tural components of nuclear reactor cores. Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries. Bwr, author, abstractnote research and testing programs to study the initiation and growth of intergranular stress corrosion cracking in bwr. Ting ting k, 1999 analyzed the crack growth due to intergranular stress corrosion cracking igscc in stainless steel piping of bwr plants. Intergranular stress corrosion cracking igscc in boiling water reactor bwr piping. Intergranular stress corrosion cracking igscc is more common than transgranular scc. Boiling water reactor bwr vessel and internals projectbwr reactor vessel instrument penetration handbook.
Irradiationinduced stress corrosion cracking of austenitic. Intergranular stress corrosion cracking in austenitic stainless steels is the major failure mode in bwr s, while it has typically not been considered as a plausible failure mode in pwr primary water under. Intergranular stress corrosion cracking igscc in boiling water. Irradiationinduced stress corrosion cracking of austenitic stainless steels. Testing sensitization and predicting susceptibility to intergranular corrosion and intergranular stress corrosion cracking in austenitic stainless steels v. Localized corrosion, and intergranular stress corrosion cracking igscc in particular, has prompted severe consequences as illustrated by the impact of welded stainless steel pipe cracking in boiling. Intergranular stress corrosion cracking of sensitized. This report begins with a brief description of the safety significance of intergranular stress corrosion cracking igscc as it. What is intergranular stress corrosion cracking igscc.
All licensees of operating boiling water reactors bwrs and holders of construction permits for bwrs subject. Intergranular stress corrosion cracking tends to occur when preexisting intergranular fractures are present. The problem of stress corrosion cracking scc, which causes sudden failure of metals and other materials subjected to stress in corrosive environments, has a significant impact on a number of. It is often caused by improper processing of the metal during manufacture or improper heat. Understanding and avoiding intergranular stress corrosion cracking of welded supermartensitic stainless steel. Small breakages are formed, they propagate in a perpendicular direction to the stress and as a result, a failure may happen. The simultaneous occurrence of three conditions are essential for the igscc in bwrs. The affecting parameters are so far not fully known. Intergranular corrosion forms along the grain structure of metal.
Comprehensive integrity assessment repair techniques 1999. Ehrnsten, u 2017, intergranular stress corrosion cracking of austenitic stainless steels. Localized corrosion, and intergranular stress corrosion cracking igscc in particular, has prompted severe consequences as illustrated by the impact of welded stainless steel pipe cracking in boilingwater reactors bwrs and steam generator tube failures in pressur ized water reactors pwrs. Intergranular stress corrosion cracking igscc of austenitic stainless steels, usually aisi 304 steel, is a serious problem in boiling water reactors bwr.
It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially. Corrosionpedia explains intergranular stress corrosion cracking igscc intergranular stress corrosion cracking is common in alloys that are otherwise typically corrosionresistant. The impact of scc on a material usually falls between dry cracking. The safety basis for rbmk reactors follows generally used safety principles of defence in depth. Probabilistic failure analysis of nuclear piping of bwr plant was carried out by you and wu you jangshyong, et al. Aug 08, 2012 the paper aims to give a present status of knowledge on irradiationassisted stress corrosion cracking iascc from the point of view of nuclear power plant life extension.